Non-Stoichiometric magnesian spinels in shale xenoliths from a native iron-bearing andesite at Asuk,Disko, central West Greenland     

Asger Ken Pedersen 《Contributions to Mineralogy and Petrology》1978,67(3):331-340

A strongly reduced native iron-bearing andesite breccia from Disko contains graphite-rich modified shale xenoliths with magnesian spinels. These spinels are free from or very poor in ferric iron and vary considerably within the MgO-FeO-Cr₂O₃-Al₂O₃ compositional space. Through a simple substitution of the type 3 (Mg, Fe)²⁺ ⇆ 2(Al, Cr)³⁺+□_vacancy, the spinels vary from stoichiometric (Mg, Fe)²⁺ (Al, Cr)³⁺ ₂O₄ towards (Al, Cr)₂O₃. The simple substitution of Cr for Al suggests that Cr was accepted into the spinel structure as Cr³⁺, despite the reduced nature of the enclosing andesite. The most magnesian spinels are cation deficient spinel_ss in the synthetic systems MgO-Al₂O₃ and MgO-Al₂O₃-Cr₂O₃. The absence of exolved (Al, Cr)₂O₃-component is probable due to rapid quenching.  相似文献   

Rb/1bSr isochrons for the granitic plutons around Farsund,southern Norway     

Svend Pedersen  Torgeir Falkum 《Chemical Geology》1975,15(2):97-101

The granitic and charnockitic intrusions in the Precambrian migmatites around Farsund in southern Norway have previously been shown to be successively intruded as well as being geochemically different. Rb- and Sr-isotope data support the conclusion that they are intruded with a separate time interval and that the Farsund charnockite is younger (852±41 m.y.) than the Lyngdal hornblende granite (932±38 m.y.). Furthermore, the different initial ratios (0.7128 and 0.7054, respectively) disprove a comagmatic origin unless large-scale contamination has occurred.  相似文献   

Electrodialytic remediation of CCA-treated waste wood in pilot scale     

Anne J. Pedersen  Iben V. Kristensen  Lisbeth M. Ottosen  Alexandra B. Ribeiro  Arne Villumsen 《Engineering Geology》2005,77(3-4):331-338

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.  相似文献   

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis   总被引：8，自引：0，他引：8  

Lisbeth M. Ottosen  Anne J. Pedersen  Alexandra B. Ribeiro  Henrik K. Hansen 《Engineering Geology》2005,77(3-4):317-329

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.  相似文献   

Late Holocene sea-level changes and isostasy in western Denmark     

W. Roland Gehrels  Katie Szkornik  Jason R. Kirby  William A. Marshall  Jørn B.T. Pedersen 《Quaternary Research》2006,66(2):288-302

Cores and exposed cliff sections in salt marshes around Ho Bugt, a tidal embayment in the northernmost part of the Danish Wadden Sea, were subjected to ¹⁴C dating and litho- and biostratigraphical analyses to reconstruct paleoenvironmental changes and to establish a late Holocene relative sea-level history. Four stages in the late Holocene development of Ho Bugt can be identified: (1) groundwater-table rise and growth of basal peat (from at least 2300 BC to AD 0); (2) salt-marsh formation (0 to AD 250); (3) a freshening phase (AD 250 to AD 1600?), culminating in the drying out of the marshes and producing a distinct black horizon followed by an aeolian phase with sand deposition; and (4) renewed salt-marsh deposition (AD 1600? to present). From 16 calibrated AMS radiocarbon ages on fossil plant fragments and 4 calibrated conventional radiocarbon ages on peat, we reconstructed a local relative sea-level history that shows a steady sea-level rise of 4 m since 4000 cal yr BP. Contrary to suggestions made in the literature, the relative sea-level record of Ho Bugt does not contain a late Holocene highstand. Relative sea-level changes at Ho Bugt are controlled by glacio-isostatic subsidence and can be duplicated by a glacial isostatic adjustment model in which no water is added to the world's oceans after ca. 5000 cal yr BP.  相似文献   

Controlled-source tensor magnetotelluric responses of a layered earth with azimuthal anisotropy   总被引：2，自引：0，他引：2  

Xiaobo Li  Laust B. Pedersen 《Geophysical Journal International》1992,111(1):91-103

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Comment on ‘Three-dimensional interpretation of multiple-source bipole-dipole resistivity data using the apparent resistivity tensor’ by H.M. Bibby and G.W. Hohmann1     

Xiaobo Li  Laust B. Pedersen 《Geophysical Prospecting》1994,42(5):525-526

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A comparison of cytochrome P4501A (CYP1A) mRNA inducibility in four species of Atlantic coast anadromous fishes     

Isaac Wirgin  Blake Konkle  Mark Pedersen  Cheryl Grunwald  Jim Williams  Simon C. Courtenay 《Estuaries and Coasts》1996,19(4):913-922

Quantification of levels of cytochrome P4501A (CYP1A) gene expression in sentinel species of fishes has been proposed as a management tool to evaluate contamination of aquatic systems. Based on preliminary studies, we hypothesized that differences in CYP1A mRNA inducibility among individuals, populations, or species might lead to spurious conclusions when using this approach in environmental monitoring programs. To address this possibility, we quantitated and compared CYP1A mRNA induction levels in four species of common Atlantic Coast estuarine fish: smooth flounder, hogchoker, striped bass, and Atlantic tomcod, which were treated with model chemicals (beta naphthoflavone (β-NF), or benzo[a]pyrene at 10 ppm) known to induce CYP1A mRNA, or were exposed to contaminated environments. Species-specific CYP1A DNA probes were generated from PCR (polymerase chain reaction) amplification of genomic DNA using conserved oligonucleotide primers, and, along with cloned rainbow trout and Atlantic tomcod CYP1A cDNA probes were used to quantify CYP1A mRNA levels in northern blot analyses. Successful PCR amplification of CYP1A hybridizable DNA fragments was observed for all four species. Results from northern blot analyses showed large differences in CYP1A mRNA induction among species; only Atlantic tomcod exhibited significant induction of CYP1A mRNA for both chemically treated (97-fold) and environmentally exposed fish (34-fold). Significant, although lower, levels of induction were observed in β-NF treated (14-fold) smooth flounder, but not in environmentally exposed smooth flounder. Only low levels (not significant) of CYP1A gene induction were detected in hogchokers and striped bass. We conclude that CYP1A mRNA inducibility differed significantly among fish taxa perhaps due to differences in regulation of gene expression, suggesting that careful selection of sentinel species should be exercised prior to the use of CYP1A mRNA induction in environmental monitoring programs. However, the significance of differences in CYP1A mRNA inducibility in relation to higher level biological endpoints has yet to be determined.  相似文献   

Atmospheric nitrogen inputs into the North Sea: effect on productivity     

Gerrit de Leeuw  Lucinda Spokes  Tim Jickells  Carsten Ambelas Skjth  Ole Hertel  Elisabetta Vignati  Susanne Tamm  Michael Schulz  Lise-Lotte Srensen  Britta Pedersen  Laura Klein  K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.  相似文献   

U/Pb ages of ophiolites and arc-related plutons of the Norwegian Caledonides: implications for the development of Iapetus     

G. R. Dunning  R. B. Pedersen 《Contributions to Mineralogy and Petrology》1988,98(1):13-23

U/Pb zircon ages are reported for four ophiolites and three crosscutting arc-related plutons from the Norwegian Caledonides. Plagiogranite differentiated from gabbro of the Karmøy ophiolite is dated at 493+7/-4 Ma whereas arc-related trondhjemite cutting this ophiolite crystallized at 485+/–2 Ma. A crosscutting clinopyroxene-phyric gabbro intrusion is dated at 470+9/–5 Ma by near concordant magmatic titanite (sphene) and discordant U-rich (2903–6677 ppm) zircon. Lower intercepts of 247+/–68 and 191+/–70 Ma defined by the plagiogranite and clinopyroxene-phyric gabbro best-fit lines may reflect a real low-T alteration/rift-related event.A plagiogranite differentiate of the Gullfjellet ophiolite complex is dated at 489+/–3 Ma and a crosscutting arc-related tonalite is 482+6/–4 Ma. Both of these ages overlap with those of the correlative rocks at Karmøy suggesting that they are parts of one ophiolitic terrane with a common history.Trondhjemite associated with the Leka ophiolite is dated at 497+/–2 Ma, indicating that supra-subduction zone magmatism there may be coeval with spreading which formed the Karmøy axis sequence.The U/Pb zircon ages of Norwegian ophiolites reported here, combined with ages of other Appalachian-Caledonian ophiolite complexes in Britain and Canada, indicate a narrow age range for the generation of at least two marginal basins in the Tremadoc-Arenig. Two spreading episodes documented at Karmøy are separated in time by intrusion of arc-related trondhjemite magmas at 485+/–2 Ma and may correlate with two separate spreading events documented in other ophiolites.The Solund/Stavfjorden ophiolite, at 443+/–3 Ma, is the only late Ordovician ophiolite yet documented in the entire Appalachian-Caledonian Orogen and it probably represents a small, short-lived marginal basin late in the history of the Iapetus Ocean. It is correlative with Caradocian ensialic marginal basin magmatism in Wales and the Trondheim region, and with tholeiitic gabbro-diorite plutons that intruded Newfoundland ophiolites in a tensional regime after emplacement of the ophiolites over the continental margin.  相似文献